BIS(2,4,6-TRIHALOPHENOXY)TRICHLOROPHOSPHORANES: NOVEL CONDENSING REAGENTS FOR INTERNUCLEOTIDIC PHOSPHOTRIESTER BOND FORMATION VIA ACTIVE PHOSPHOROCHLORIDATE INTERMEDIATES

DOI: 10.1016/S0040-4039(00)85289-2

Source and publish data:

Tetrahedron Letters p. 5645 - 5648 (1986)

Update date:2022-08-04

Topics:

Authors:

Matsuzaki, Jun-ichi

Hotoda, Hitoshi

Sekine, Mitsuo

Hata, Tsujiaki

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Article abstract of DOI:10.1016/S0040-4039(00)85289-2

New types of reagents, bis(2,4,6-trihalophenoxy)trichlorophosphoranes, were very effective as condensing agents for internucleotidic bond formation in the phosphotriester method.The ³¹P NMR study showed that the condensation proceeded via phosphorochloridate intermediates.

Full text of DOI:10.1016/S0040-4039(00)85289-2

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