BIS(2,4,6-TRIHALOPHENOXY)TRICHLOROPHOSPHORANES: NOVEL CONDENSING REAGENTS FOR INTERNUCLEOTIDIC PHOSPHOTRIESTER BOND FORMATION VIA ACTIVE PHOSPHOROCHLORIDATE INTERMEDIATES

DOI: 10.1016/S0040-4039(00)85289-2

Source and publish data:

Tetrahedron Letters p. 5645 - 5648 (1986)

Update date:2022-08-04

Topics:

Authors:

Matsuzaki, Jun-ichi

Hotoda, Hitoshi

Sekine, Mitsuo

Hata, Tsujiaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85289-2

New types of reagents, bis(2,4,6-trihalophenoxy)trichlorophosphoranes, were very effective as condensing agents for internucleotidic bond formation in the phosphotriester method.The ³¹P NMR study showed that the condensation proceeded via phosphorochloridate intermediates.

Full text of DOI:10.1016/S0040-4039(00)85289-2

Products guided by the article

Product name:bis(2,4,6-trichlorophenoxy)trichlorophosphorane

Cas No:109714-30-9

R&D Labs maybe for 109714-30-9

Sino-Japan Chemical Co., Ltd.

website:http://www.sjc.com.tw

Contact:(886) 2-2396-6223

Address:14Fl., No. 99. Sec. 2, Jen Ai Road
AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
Jiaxing Trustworthy Import And Export Co.,Ltd

Contact:+86-573-82030555

Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
Chengdu Yunyi International Trade Co., Ltd

Contact:

Address:china
guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129

Relevant to this article

Organopalladium approaches to prostaglandins. 4. Synthesis of the first interphenylene PGH₂ analogs via benzylpalladation

Doi:10.1016/S0040-4039(00)94905-0
(1985)
Cu(I)-assisted carbon-carbon bond forming reactions of γ,γ-dialkoxyallylic zirconium species: A new versatile homoenolate equivalent of propionate

Doi:10.1016/S0040-4039(00)01822-0
(2000)
A major decomposition product, citrinin H2, from citrinin on heating with moisture.

Doi:10.1271/bbb.66.206
(2002)
Determination and characterization of unreacted hydroxyl groups in a cross-linked poly(ortho ester)

Doi:10.1021/ac00092a033
(1994)
Palladium-catalyzed domino Mizoroki-Heck/intermolecular C(sp³)-H activation sequence: An approach to the formation of C(sp³)-C(sp³) bonds

Doi:10.1002/ejoc.201500116
(2015)
Total Synthesis of (+)-Latrunculin A, an Ichthyotoxic Metabolite of the Sponge Latrunculia magnifica, and Its C-15 Epimer

Doi:10.1021/jo00046a008
(1992)

Article Doi