BIS(2,4,6-TRIHALOPHENOXY)TRICHLOROPHOSPHORANES: NOVEL CONDENSING REAGENTS FOR INTERNUCLEOTIDIC PHOSPHOTRIESTER BOND FORMATION VIA ACTIVE PHOSPHOROCHLORIDATE INTERMEDIATES

DOI: 10.1016/S0040-4039(00)85289-2

Source and publish data:

Tetrahedron Letters p. 5645 - 5648 (1986)

Update date:2022-08-04

Topics:

Authors:

Matsuzaki, Jun-ichi

Hotoda, Hitoshi

Sekine, Mitsuo

Hata, Tsujiaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85289-2

New types of reagents, bis(2,4,6-trihalophenoxy)trichlorophosphoranes, were very effective as condensing agents for internucleotidic bond formation in the phosphotriester method.The ³¹P NMR study showed that the condensation proceeded via phosphorochloridate intermediates.

Full text of DOI:10.1016/S0040-4039(00)85289-2

Products guided by the article

Product name:bis(2,4,6-trichlorophenoxy)trichlorophosphorane

Cas No:109714-30-9

R&D Labs maybe for 109714-30-9

CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Shandong united-rising pharmaceutical cooperation.,ltd.

Contact:008653187965009

Address:171No., Jing5 Road, Shizhong District, Jinan, China
MENGNA

Contact:18698110882

Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road

Relevant to this article

Organopalladium approaches to prostaglandins. 4. Synthesis of the first interphenylene PGH₂ analogs via benzylpalladation

Doi:10.1016/S0040-4039(00)94905-0
(1985)
Cu(I)-assisted carbon-carbon bond forming reactions of γ,γ-dialkoxyallylic zirconium species: A new versatile homoenolate equivalent of propionate

Doi:10.1016/S0040-4039(00)01822-0
(2000)
A major decomposition product, citrinin H2, from citrinin on heating with moisture.

Doi:10.1271/bbb.66.206
(2002)
Determination and characterization of unreacted hydroxyl groups in a cross-linked poly(ortho ester)

Doi:10.1021/ac00092a033
(1994)
Palladium-catalyzed domino Mizoroki-Heck/intermolecular C(sp³)-H activation sequence: An approach to the formation of C(sp³)-C(sp³) bonds

Doi:10.1002/ejoc.201500116
(2015)
Total Synthesis of (+)-Latrunculin A, an Ichthyotoxic Metabolite of the Sponge Latrunculia magnifica, and Its C-15 Epimer

Doi:10.1021/jo00046a008
(1992)

Article Doi