SYNTHESIS AND REACTIONS OF PHOSPHIDO-BRIDGED μ3-ALKYLIDYNE CLUSTERS; X-RAY CRYSTAL STRUCTURES OF THE COMPLEXES , (μ-CO)(CO)4(PPh2)(η-C5H5)>, AND (CO)4(η-C5H5)>

Article abstract of DOI:10.1016/0022-328X(86)80267-4

Reactions of the phosphido-bridged complexes (R=Ph or Et) with PR2H (R=Ph or Et) or RC<*>CR (R=Me or Et) are dominated by processes involving facile P-C, C-C and C-H bond formation.The X-ray structures of the