Journal of Organic Chemistry p. 715 - 717 (1994)
Update date:2022-07-29
Topics:
Sasaki, Makoto
Inoue, Masayuki
Tachibana, Kazuo
The first stereoselective synthesis of the KLM ring fragment of ciguatoxin is reported including as a key step 7-endo selective cyclization of epoxy alcohol to construct a fully substituted oxepane ring (12 -> 13).
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Doi:10.1021/jm9606406
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