Tetrahedron Asymmetry p. 1 - 4 (1994)
Update date:2022-08-05
Topics:
Perard-Viret
Rassat
Optically pure bicylo[3.3.0]octane-2,6-dione is easily obtained with a yield of 4 % for each enantiomer from 1,5-cyclooctadiene in 5 steps, by resolution of the intermediate diol with menthyloxyacetic acid. Its CD is 60 % larger than twice the CD of a corresponding monoketone indicating interactions between non-conjugated chromophores.
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(2015)Doi:10.1021/jo802303m
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(2007)Doi:10.1021/acsinfecdis.0c00915
(2021)Doi:10.1016/j.tetasy.2008.10.030
(2008)
