Tetrahedron Letters p. 397 - 400 (1987)
Update date:2022-07-30
Topics:
Differding, Edmond
Vandevelde, Oscar
Roekens, Bertrand
Van, Tran Trieu
Ghosez, Leon
Allylic cyanides are readily silylated by triisopropylsilyl chloride to give alkenyl ketenimines 1.The reaction of 1 with acetylenic dienophiles followed by desilylation leads to the formation of substituted anilines with complete regioselectivity.
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