Bulletin of the Chemical Society of Japan p. 2669 - 2678 (1995)
Update date:2022-08-02
Topics:
Takeshita, Hitoshi
Mori, Akira
Kato, Nobuo
Kurahashi, Yoichi
Ito, Masahito
High-pressure Diels-Alder reaction of cyclooctatetraene with dimethyl 1,4-dimethyl-7-oxabicyclo<2.2.1>-hepta-2,5-diene-2,3-dicarboxylate afforded six products, one of which was shown to be a 2:2-adduct having a syn-tricyclo<4.2.0.02,5>octane framework.Upon radiation with X-rays, the tricyclooctane derivative isomerized to a cyclooctadiene derivative.
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