Synthesis of carbacephem antibiotics: Synthesis via Dieckmann reaction using phenyl esters to direct the regioselectivity of the cyclization

DOI: 10.1016/S0040-4039(00)97052-7

Source and publish data:

Tetrahedron Letters p. 6317 - 6320 (1990)

Update date:2022-08-04

Topics:

Authors:

Jackson, Bill G.

Gardner, John P.

Heath, Perry C.

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Article abstract of DOI:10.1016/S0040-4039(00)97052-7

β-Ketoesters useful for elaboration to carbacephems were synthesized from a variety of enantiomerically pure diesters. Use of phenyl esters to direct the regioselectivity was demonstrated.

Full text of DOI:10.1016/S0040-4039(00)97052-7

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