Journal of the American Chemical Society p. 8430 - 8438 (1989)
Update date:2022-07-29
Topics: Total synthesis Remote Stereocontrol
Vedejs, E.
Buchanan, R. A.
Watanabe, Y.
The details for the conversion of 1 into d,l-methynolide are described.Key steps include the highly selective reduction to alcohol 3, the oxidation α to sulfide sulfur from 3 to thiolactone 13, and the acyl transfer from 14 to the lactone 16.Photochemical
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