Journal of Organometallic Chemistry p. 1 - 8 (1986)
Update date:2022-09-26
Topics:
Haubold, Wolfgang
Herdtle, Joerg
Gollinger, Walter
Einholz, Wolfgang
In a ligand-exchange reaction between aryltrimethylsilanes, (ArSiMe3) and halogenboranes, (BX3 or ArBX2), arylhalogenboranes (ArBX2, ArAr'BX or Ar2BX) and halogentrimethylsilane are formed.This transfer of substituted aromatic groups from a silicon to a boron atom is an efficient synthetic pathway for the preparation of the corresponding arylhalogenboranes and diarylhalogenboranes with different aryl groups.Physical properties and spectroscopical data of the new arylhalogenboranes are given.
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