STEREOSELECTIVE SYNTHESIS OF α-D-GLUCOPYRANOSIDES VIA 6-SILYL-α-D-GLUCOPYRANOSYL BROMIDES

DOI: 10.1016/S0040-4039(01)81005-4

Source and publish data:

Tetrahedron Letters p. 849 - 852 (1987)

Update date:2022-08-05

Topics:

Authors:

Fei, C. P.

Chan, T. H.

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Article abstract of DOI:10.1016/S0040-4039(01)81005-4

Bromotrimethylsilane cleaved 2,3,4-tri-O-benzyl-1,6-anhydro-β-D-glucopyranose (1) to give 2,3,4-tri-O-benzyl-6-O-trimethylsilyl-α-D-glucopyranosyl bromide (2).Reaction of 2 with ROH/diisopropylethylamine gave the corresponding α-glucopyranosides.

Full text of DOI:10.1016/S0040-4039(01)81005-4

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