Synthesis of Enantiomerically Enriched α-Sulfenylated Ketones and Aldehydes

DOI: 10.1055/s-1987-27870

Source and publish data:

Synthesis p. 159 - 161 (1987)

Update date:2022-07-29

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Authors:

Youn, Joo-Hack

Herrmann, Rudolf

Ugi, Ivar

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Article abstract of DOI:10.1055/s-1987-27870

α-Sulfenylated carbonyl compounds are prepared by the reaction of imines of aldehydes and ketones containing α-hydrogens with disulfides via the metalloenamines.With (R)-α-phenylethylamine as chiral auxiliary, enantiomeric excess of 13-51percent are obser

Full text of DOI:10.1055/s-1987-27870

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