Journal of the Chemical Society. Chemical communications p. 109 - 110 (1987)
Update date:2022-07-29
Topics: Synthesis Intermediates Paal-Knorr Synthesis 1,4-diketones
Chiu, Pak-Kan
Lui, Kon-Hung
Maini, Prem Nath
Sammes, Michael P.
Reaction of 2,2-dimethyl-1,4-diketones with liquid ammonia gives high yields of isolable 2-hydroxy-3,4-dihydro-2H-pyrroles (3) and (5) which are readily dehydrated to give separable mixtures of 3H-pyrroles and methylenedihydropyrroles, while less-substituted 1,4-diketones give analogous hydroxy-compounds (4) and (6) which are hitherto-unsuspected intermediates in the Paal-Knorr 1H-pyrrole synthesis.
View MoreSHANGHAI SYSTEAM BIOCHEM CO., LTD
website:http://www.systeambc.com
Contact:86-021-58380978
Address:Building 87，Lane 669， Dong Jing Road Shanghai,P.R.China
Qingdao Kylin Trading Co., Ltd.
Contact:0086-532-68979884/58972912/68972263/65/88171519
Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Shanghai HengXun Pharmaceutical Tech. Co., Ltd.
Contact:86-86-52730756
Address:Room 603, No. 240, Tianmuzhong Road, Zhabei, Shanghai, China
Contact:+86-518-81061113
Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
HANGZHOU YUNUO CHEMICAL CO.,LTD
website:http://www.yunuochem.com
Contact:0571-83715115
Address:hangzhou
Doi:10.1055/s-1986-31830
(1986)Doi:10.1007/s10593-007-0216-5
(2007)Doi:10.1016/S0040-4039(00)85252-1
(1986)Doi:10.1002/poc.1414
(2009)Doi:10.1021/ja00259a024
(1987)Doi:10.1002/anie.201205498
(2012)
