Conformational Preference in 1,3-Dithianes Containing 2-Phosphoryl, -(thiophosphoryl), and -(selenophosphoryl) groups. Chemical and Crystallographic Implications of the Nature of the Anomeric Effect

DOI: 10.1021/jo00086a016

Source and publish data:

Journal of Organic Chemistry p. 1672 - 1693 (1994)

Update date:2022-08-04

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Authors:

Mikolajczyk, Marian

Graczyk, Piotr P.

Wieczorek, Michal W.

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Article abstract of DOI:10.1021/jo00086a016

The operation of anomeric effect in all the title compounds studied was found.The magnitude of the anomeric effect was found to be larger than 10 kJ/mol.Crystallographic, spectroscopic, and thermodynamic data suggest that n_S-?^*_C

Full text of DOI:10.1021/jo00086a016

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