NOVEL Si-C BOND CLEAVAGES OF ALKYLIDINESILIRANES IN THE REACTION WITH NUCLEOPHILES

DOI: 10.1016/S0040-4020(01)80056-9

Source and publish data:

Tetrahedron p. 1929 - 1940 (1989)

Update date:2022-08-03

Topics:

Authors:

Saso, Haruo

Ando, Wataru

Ueno, Katsuhiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80056-9

1,1-Dimesityl-2-Z-neopentylidenesilirane (1Z) reacted with nucleophiles to give ring opening adducts inserting at unexpected Si-C2 bond.This behavior can be explained by the unique stuctural feature of 1Z defined by its X-ray crystal analysis.A six electr

Full text of DOI:10.1016/S0040-4020(01)80056-9

Products guided by the article

Product name:(Z)-1,1-dimesityl-2-neopentylidenesilirane

Cas No:110547-61-0

R&D Labs maybe for 110547-61-0

Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
ZHUHAI HAIRUIDE BIOSCIENCE AND TECHNOLOGY CO.,LTD

website:http://www.zhhairuide.com

Contact:+8613326687259/+86-756-7789199

Address:No.10 Yonghui Road
Jiangsu Mingchem Corporation

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
zonk drug r&d limited

Contact:+86-20-32051076

Address:1105,Building A, International Business Incubator,Science City
Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.

Relevant to this article

N-(retinoyl)amino acids, synthesis and chemopreventive activity in vitro

Doi:10.1021/jm00396a031
(1988)
<2+3> CYCLOPENTENE ANNULATION AND OTHER TRIMETHYLSILYL IODIDE-MEDIATED REARRANGEMENT PATHWAYS OF VINYLCYCLOPROPANES

Doi:10.1016/S0040-4039(00)95677-6
(1987)
Synthesis, molecular modeling studies, and anticonvulsant evaluation of novel 1-((2-hydroxyethyl)(aryl)amino)-N-substituted cycloalkanecarboxamides and their acetate esters

Doi:10.1002/ardp.201800269
(2018)
ASYMMETRIC TOTAL SYNTHESIS OF 14(R),15(S)-, 14(S),15(R)-, 14(R),15(R)-, AND 14(S),15(S)-EPOXYEICOSATRIENOIC ACIDS

Doi:10.1016/S0040-4039(00)85390-3
(1986)
Investigation of the mechanism of dissociation of glycolaldehyde dimer (2,5-dihydroxy-1,4-dioxane) by FTIR spectroscopy

Doi:10.1016/S0008-6215(98)00129-3
(1998)
Synthesis, characterization, structures and comparative electrochemical study of 2,4-bis(trimethylsilylethynyl)thiophene coordinated carbonylcobalt units

Doi:10.1002/ejic.200700453
(2007)

Article Doi