NOVEL Si-C BOND CLEAVAGES OF ALKYLIDINESILIRANES IN THE REACTION WITH NUCLEOPHILES

DOI: 10.1016/S0040-4020(01)80056-9

Source and publish data:

Tetrahedron p. 1929 - 1940 (1989)

Update date:2022-08-03

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Authors:

Saso, Haruo

Ando, Wataru

Ueno, Katsuhiko

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Article abstract of DOI:10.1016/S0040-4020(01)80056-9

1,1-Dimesityl-2-Z-neopentylidenesilirane (1Z) reacted with nucleophiles to give ring opening adducts inserting at unexpected Si-C2 bond.This behavior can be explained by the unique stuctural feature of 1Z defined by its X-ray crystal analysis.A six electr

Full text of DOI:10.1016/S0040-4020(01)80056-9

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