Construction of Five-Membered Rings by Michael Addition-Radical Cyclization

DOI: 10.1021/jo00231a021

Source and publish data:

Journal of Organic Chemistry p. 4943 - 4953 (1987)

Update date:2022-08-02

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Authors:

Clive, Derrick L.J.

Boivin, Taryn L.B.

Angoh, A. Gaeetan

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Article abstract of DOI:10.1021/jo00231a021

Enamines react with Michael acceptors 8-10 to produce ketones that, on treatment with lithium acetylides, afford hydroxy acetylenes 3.These compounds then undergo radical cyclization when treated with triphenyltin hydride and AIBN.The products 6 are forme

Full text of DOI:10.1021/jo00231a021

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