Tetrahedron p. 323 - 332 (1987)
Update date:2022-07-29
Topics:
Barton, Derek H. R.
Yadav-Bhatnagar, Neerja
Finet, Jean-Pierre
Khamsi, Jamal
Motherwell, William B.
Stanforth, Stephen P.
The influence of the substituents on the phenol on the regiochemistry of the arylation reactions with Ph3BiCl2 and other bismuth reagents has been studied.O-Phenylation occurs with phenols substituted with electron-withdrawing groups.Electron-donating substituted phenols undergo ortho C-phenylation.Oxidative dimerisation has been observed with 2,6-dialkyl phenols.
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(2007)