Chemistry Letters p. 1329 - 1332 (1986)
Update date:2022-08-04
Topics:
Satoh, Makoto
Miyaura, Norio
Suzuki, Akira
The reaction of diisopropyl (Z)-(1-bromo-1-alkenyl)boronates readily obtainable, with organolithiums and bases takes place readily to give (E)-(1-organo-1-alkenyl)boronates, the cross-coupling of which with various organic halides proceeds smoothly in the presence of Pd-catalyst and base to afford stereodefinied trisubstituted alkenes in good yields.
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