Journal of the Chemical Society, Dalton Transactions p. 1393 - 1400 (1992)
Update date:2022-08-04
Topics:
Alsina, Teresa
Clegg, William
Fraser, Kelly A.
Sola, Joan
The complexes Hg(SR)2 1 and a polymeric structure consisting of rather bent Hg(SR)2 units a very asymmetric bridge between two Hg atoms.Complex 2 contains Hg atoms in a distorted trigonal-planar co-ordination environment, the monomeric anions being well separated from each other.The distorsion is mostly in-plane, producing one angle considerably less than, and one considerably greater than, the ideal 120 deg; the largest angle lies opposite the longest Hg-S bond, and the smallest angle opposite the shortest Hg-S bond.Proton and 13C NMR, far-IR and Raman, and low-energy UV spectroscopic data are discussed.The UV data afford additional support for the proposal of a trigonal-planar A correlation of co-ordination geometry, Hg-S bond lengths, and Hg-S stretching frequencies is developed for these and other homoleptic thiolate complexes of mercury.
Contact:+86-10-62651721
Address:29 Yongxing Road, Daxing District,Beijing China
Contact:+86-519-86623222
Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
MTT Pharma & Bio-technology Co.,Ltd(expird)
Contact:+86-21-58407925
Address:Room2019, Building C, Tomson Center, No.158, Zhang Yang Road, Shanghai, China
website:http://www.tcfinechem.com/
Contact:18681346930
Address:baifu town,whou district
lianyungang jinkang pharmaceutical technology co., ltd.
Contact:008651885445517
Address:Jinshan industrial park, Ganyu county, Lianyungang, Jiangsu Province, 222115, China
Doi:10.1016/j.tetlet.2008.10.102
(2009)Doi:10.1111/cbdd.13586
(2020)Doi:10.1021/om800863t
(2009)Doi:10.1021/jo01088a609
(1959)Doi:10.1016/S0040-4039(01)81034-0
(1987)Doi:10.1002/adma.202001592
(2020)
