Journal of the Chemical Society. Chemical communications p. 1782 - 1783 (1986)
Update date:2022-08-05
Topics:
Brueckmann, Ralf
Maas, Gerhard
Thermolysis of the α-silylated α-diazoketone (1) at 80 deg C generates the electron-rich heptafulvene (2); the alkylidenecarbene (5) is the key intermediate of the reaction sequence.
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