Hydrogen Bonding in Imidazolium Salts and its Implications for Ambient-temperature Halogenoaluminate(III) Ionic Liquids

DOI: 10.1039/DT9950003467

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3467 - 3472 (1995)

Update date:2022-08-05

Topics:

Authors:

Elaiwi, Ahmed

Hitchcock, Peter B.

Seddon, Kenneth R.

Srinivasan, Narmatha

Tan, Yu-May

et al. et al.

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Article abstract of DOI:10.1039/DT9950003467

The salts X (X = Br or I, emim = 1-ethyl-3-methylimidazolium) and have been prepared as solid-state models of the X-AlX3 (X = Cl or Br) ionic liquid systems.All three have been characterised crystallographically.The salts X (X = Br or I) are isomorphous and are composed of ions in an extended hydrogen-bonded network.The implications of these results for both the structure and solvent properties of the ionic liquids are discussed.

Full text of DOI:10.1039/DT9950003467

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