Group 5 metallocene complexes as models for Metal-Mediated hydroboration: Synthesis of a reactive borane adduct, endo-Cp*2Nb(H2BO2C6H4), via hydroboration of coordinated olefins

DOI: 10.1021/ja970639b

Source and publish data:

Journal of the American Chemical Society p. 9699 - 9708 (1997)

Update date:2022-09-26

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Authors:

Lantero, Dean R.

Ward, Donald L.

Smith III, Milton R.

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Article abstract of DOI:10.1021/ja970639b

The olefin complexes Cp*₂M(CH₂=CH(R))(H) (R = H (1), CH₃ (2); M = Nb (a), Ta (b)) react cleanly with catecholborane (HBCat) and HBO₂C₆H₃-4-(t)Bu (HBCat') to give Cp*₂M(H_{2
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Full text of DOI:10.1021/ja970639b

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