Silicon-Directed Stereoselective Synthesis of 2-vinyl-1,3-diols. Stereo-Divergence with and without the silyl Group Related to the Synthesis of Avenaciolide and Isoavenaciolide

DOI: 10.1016/S0040-4020(01)86656-4

Source and publish data:

Tetrahedron p. 4061 - 4072 (1988)

Update date:2022-07-31

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Authors:

Suzuki, Keisuke

Miyazawa, Mayumi

Shimazaki, Masato

Tsuchihashi, Gen-ichi

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Article abstract of DOI:10.1016/S0040-4020(01)86656-4

A flexible approach to the stereoisomers of 2-vinyl-1,3-diols via the reduction of 2-vinyl aldols is described.The presence of the TMS group at the α-position of the vinyl group firmly establishes the syn relationship between the newly-formed hydroxyl gro

Full text of DOI:10.1016/S0040-4020(01)86656-4

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