Tetrahedron p. 4061 - 4072 (1988)
Update date:2022-07-31
Topics:
Suzuki, Keisuke
Miyazawa, Mayumi
Shimazaki, Masato
Tsuchihashi, Gen-ichi
A flexible approach to the stereoisomers of 2-vinyl-1,3-diols via the reduction of 2-vinyl aldols is described.The presence of the TMS group at the α-position of the vinyl group firmly establishes the syn relationship between the newly-formed hydroxyl gro
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