4-OXY-SUBSTITUTED 1-LITHIO-1,2-ALKADIENYL CARBAMATES: TRAPPING OF CONFIGURATIVELY STABLE ALLENIC CARBANIONS AND STEREOSPECIFIC 1,4-ELIMINATION FOR THE SYNTHESIS OF ALK-3-EN-1-YNYL CARBAMATES.

DOI: 10.1016/S0040-4039(01)80989-8

Source and publish data:

Tetrahedron Letters p. 785 - 788 (1987)

Update date:2022-09-26

Topics:

Authors:

Hoppe, Dieter

Gonschorrek, Charlotte

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)80989-8

4-Silyloxy-1,2-alkadienyl carbamates 10 on treatment with n-butyllithium form 1-lithio derivatives 12 of moderate configurative stability.After replacement of silyloxy for the better leaving group benzoyloxy in 11, anions 15 undergo stereospecific 1,4-eli

Full text of DOI:10.1016/S0040-4039(01)80989-8

Products guided by the article

Product name:Benzoic acid 4-diisopropylcarbamoyloxy-1,2-dimethyl-buta-2,3-dienyl ester

Cas No:111572-66-8

R&D Labs maybe for 111572-66-8

Anhui Hope-Chem Co., Ltd.

Contact:86-551-63540590

Address:No 1388 Furong Rd., Hefei, Anhui, China
Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
hangzhou verychem science and technology co.ltd

website:http://www.verypharm.com

Contact:+86-571-88162785; 88162786

Address:F1502, 753 Shenhua road, Hangzhou, China
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian
Debye Scientific

website:http://www.debyesci.com

Contact:+85221376140

Address:Rm. 19C, Lockhart Ctr., 301-307 Lockhart Rd., Wan Chai

Relevant to this article

CATALYTIC ASYMMETRIC SYNTHESIS OF DIPEPTIDES FROM 2-TRIFLUOROMETHYL-Δ²- AND 2-TRIFLUOROMETHYL-Δ³-OXAZOLIN-5-ONES

Doi:10.1007/BF00959378
(1987)
Cyclopropanation of Electrophilic Alkenes With Nitroalkanes in the Presence of Alumina-Supported Potassium Fluoride

Doi:10.1055/s-1987-27944
(1987)
Synthesis of mammeins and surangin A

Doi:10.1016/S0040-4039(00)98874-9
(1985)
Synthesis and phase behavior of new isoflavone derivatives: Crystal structure of 7-hexyloxy-3-[4′-(3-methylbutyloxy)phenyl]-4H-1-benzopyran-4- one

Doi:10.1080/15421400801914723
(2008)
Easy access to cis-3-(benzoxazol-2-yl)cyclopentanecarboxylic acids from camphorquinone and o-aminophenols via an unexpected opening of camphor ring

Doi:10.1080/00397911.2012.696302
(2013)
Synthesis and characterization of novel donor-acceptor type neutral green electrochromic polymers containing an indolo[3,2-: B] carbazole donor and diketopyrrolopyrrole acceptor

Doi:10.1039/c8ra03552k
(2018)

Article Doi