Cyclopropanation of Electrophilic Alkenes With Nitroalkanes in the Presence of Alumina-Supported Potassium Fluoride

DOI: 10.1055/s-1987-27944

Source and publish data:

Synthesis p. 364 - 366 (1987)

Update date:2022-09-26

Topics:

Authors:

Melot, Jean-Marie

Texier-Boullet, Francoise

Foucaud, Andre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1987-27944

Alumina-supported potassium fluoride is an effective reagent for Michael addition of nitroalkanes on the electrophilic alkenes, followed by cycloalkylation reaction to give cyclopropanes.

Full text of DOI:10.1055/s-1987-27944

Products guided by the article

Product name:Propanedioic acid, [2-methyl-2-nitro-1-(4-nitrophenyl)propyl]-, dimethyl ester

Cas No:111735-90-1

R&D Labs maybe for 111735-90-1

Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
Jinan Jinguilin Chemical Co.,Ltd

Contact:+86-531-81188412

Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Nanjing Vincero International Trading Co.,Ltd

Contact:8618936897229

Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China

Relevant to this article

Reactions of methylene active compounds with peroxorhodium phosphino complexes. Formation of hydroperoxorhodium complexes

Doi:10.1016/0022-328X(87)85101-X
(1987)
Fast, acid-free, and selective lactamization of lactones in ionic liquids

Doi:10.1021/jo8015264
(2008)
Substituent Effects on the Populations of Rotational Isomers in 9-(Aryloxymethyl)-1,4-dimethyltriptycenes. Implications for the Presence of CH3...O Hydrogen Bond

Doi:10.1246/cl.1986.1619
(1986)
Photoinduced Intramolecular Electron Transfer in Peptide-Bridged Molecules

Doi:10.1021/ja00212a029
(1988)
Novel substituted triazolo benzodiazepine scaffolds to explore chemical space

Doi:10.1016/j.tetlet.2021.152828
(2021)
Singel-Oxygen Photolysis of Dihaloketones. A Facile and Efficient Approach to Vicinal Triketones and Their Monohydrates

Doi:10.1055/s-1987-27986
(1987)

Article Doi