DIASTEREOSELECTIVE ?-FACIALLY CONTROLLED NUCLEOPHILIC ADDITIONS OF CHIRAL VINYLORGANOMETALLICS TO CHIRAL β,γ-UNSATURATED KETONES. 2. A PRACTICAL METHOD FOR STEREOCONTROLLED ELABORATION OF THE DECAHYDRO-as-INDACENE SUBUNIT OF IKARUGAMYCIN

DOI: 10.1016/S0040-4039(00)95641-7

Source and publish data:

Tetrahedron Letters p. 31 - 34 (1987)

Update date:2022-07-30

Topics:

Authors:

Paquette, Leo A.

Romine, Jeffrey L.

Lin, Ho-Shen

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Article abstract of DOI:10.1016/S0040-4039(00)95641-7

7,7-Dimethoxy-5-norbornen-2-one has been converted in 7 steps to tricyclic enone 10, which comprises a principal subunit of the ikarugamycin structure.

Full text of DOI:10.1016/S0040-4039(00)95641-7

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