Journal of the Chemical Society. Chemical communications p. 794 - 796 (1987)
Update date:2022-08-04
Topics:
Casiraghi, Giovanni
Cornia, Mara
Casnati, Giuseppe
Fava, Giovanna Gasparri
Belicchi, Marisa Ferrari
Zetta, Lucia
Complementary diastereoselectivity in the C-arylation of (R)- and (S)-2,3-O-isopropylideneglyceraldehyde by using Mg2+-based (syn-addition) and Ti4+-based (anti-addition) phenolates allows the efficient preparation of all four possible stereoisomers of the title 1-C-substituted glycerols; the application of ultrasonic waves produces a marked synthetic advantage.
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