TANDEM RADICAL CYCLISATION - INTRAMOLECULAR MUKAIYAMA ALDOLISATION APPROACH TO FORSKOLIN

DOI: 10.1016/S0040-4039(00)95357-7

Source and publish data:

Tetrahedron Letters p. 1313 - 1316 (1987)

Update date:2022-08-04

Topics:

Authors:

Hutchinson, John H.

Pattenden, Gerald

Myers, Peter L.

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Article abstract of DOI:10.1016/S0040-4039(00)95357-7

The trans-decalin lactone (11), an advanced intermediate towards forskolin (1), has been elaborated in five steps from the bromo-acetal (4) using a novel stereoselective intramolecular radical mediated cyclisation reaction, viz. (4) -> (5), in tandem with

Full text of DOI:10.1016/S0040-4039(00)95357-7

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