Generation of aluminum and Aluminum Allenoates by the Hydroalumination of α,β-Acetylenic Carbonyl Compounds and Their Reaction with Carbonyl Compounds

DOI: 10.1021/jo00240a020

Source and publish data:

Journal of Organic Chemistry p. 1037 - 1040 (1988)

Update date:2022-08-02

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Authors:

Tsuda, Tetsuo

Yoshida, Tsutomu

Saegusa, Takeo

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Article abstract of DOI:10.1021/jo00240a020

<α-(Alkoxycarbonyl)vinyl>aluminum and aluminum allenolate intermediates were generated by the hydroalumination of α,β-acetylenic ester and ketone, respectively, with DIBAH-HMPA.The <α-(methoxycarbonyl)vinyl>aluminum generated from methyl propynoate reacte

Full text of DOI:10.1021/jo00240a020

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