Ruthenium(II)- and Rhenium(III)-catalysed Addition of Tetrahalogenomethanes to Alkenes and 1,ω-Dienes. Stereoselective Formation of cis-1,2-Disubstituted Cyclopentanes from 1,6-Dienes

DOI: 10.1039/P19870001515

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1515 - 1520 (1987)

Update date:2022-08-03

Topics:

Authors:

Grigg, Ronald

Devlin, John

Ramasubbu, Ashok

Scott, Ronald M.

Stevenson, Paul

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Article abstract of DOI:10.1039/P19870001515

Acetonitrile(trichloro)bis(triphenylphosphine)rhenium(III) is found to act as an initiator for the addition of carbon tetrachloride and bromotrichloromethane to terminal alkenes an dienes.Moderate to good yields of mono- and bis-adducts are obtained. 1,6-

Full text of DOI:10.1039/P19870001515

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