The First Acid and Ester Enols: 2,2-Bis(pentamethylphenyl)ethene-1,1-diol and 1-t-Butoxy-2,2-bis(pentamethylphenyl)ethenol, and Their Oxidation to Stable Free Radicals

DOI: 10.1039/c39870000744

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 744 - 745 (1987)

Update date:2022-08-04

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Authors:

O'Neill, Patrick

Hegarty, Anthony F.

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Article abstract of DOI:10.1039/c39870000744

Desilylation of the ketene acetals (5) and (9) provides the ene-1,1-diols (6) and (10) which undergo relatively slow ketonisation and are oxidized to stable free radicals in basic solution.

Full text of DOI:10.1039/c39870000744

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