Synthesis and hydroboration/oxidation of tricyclo(5.2.1.04,10)dec-8-ene-2,5-dione(bis-acetal): new synthetic entry to tricyclo(5.2.1.04,10)decane-2, 5, 8-trione

DOI: 10.1016/S0040-4020(01)86796-X

Source and publish data:

Tetrahedron p. 2147 - 2156 (1987)

Update date:2022-09-26

Topics:

Authors:

Carceller, Elena

Garcaia, M.Llutsa

Serratosa, Felix

Font-Altaba, Manuel

Solans, Xavier

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Article abstract of DOI:10.1016/S0040-4020(01)86796-X

Tricyclo(5.2.1.0^4,10)decane-2,5,8-trione (4) has been synthesized from the corresponding bis-acetal of the unsaturated diketone 20 by a hydroboration/oxidation/deprotection sequence.

Full text of DOI:10.1016/S0040-4020(01)86796-X

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Product name:exo-9-phenylselenotricyclo(5.2.1.0^4,10)decan-2,5-dione, bis(2,2-dimethyltrimethylene)acetal

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