Chemistry Letters p. 983 - 986 (1987)
Update date:2022-08-03
Topics:
Sakurai, Hideki
Sakamoto, Kenkichi
Kira, Mitsuo
Dibenzodisilacyclohexadiene reacts with ketones and formaldehyde, under photolytic coditions, to give a variety of products depending on the nature of the ketones used.A compound having 2-sila-3-oxabicyclo<3.2.2>nona-6,8-diene structure was isolated as a result of intramolecular trapping of a cyclohexadienyl radical.
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