Indium-mediated reaction of 1,3-dichloro- and 1,3-dibromopropenes with carbonyl compounds. Generation of novel 3,3-diindiopropene

DOI: 10.1016/0040-4039(96)01925-9

Source and publish data:

Tetrahedron Letters p. 8417 - 8420 (1996)

Update date:2022-09-26

Topics:

Authors:

Araki, Shuki

Hirashita, Tsunebisa

Shimizu, Hidetaka

Yamamura, Hatsuo

Kawai, Masao

Butsugan, Yasuo

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Article abstract of DOI:10.1016/0040-4039(96)01925-9

Indium-mediated reaction of 1,3-dichloropropene with aldehyde gave syn-chlorohydrin predominantly. A similar reaction of 1,3-dibromopropene gave vinyloxirane and homoallyl alcohol; the former is formed from γ-bromoallylindium via the corresponding bromohydrin, and the latter is considered to be derived from a unique allylic diindium reagent, 3,3-diindiopropene.

Full text of DOI:10.1016/0040-4039(96)01925-9

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