Tetrahedron Letters p. 8417 - 8420 (1996)
Update date:2022-09-26
Topics:
Araki, Shuki
Hirashita, Tsunebisa
Shimizu, Hidetaka
Yamamura, Hatsuo
Kawai, Masao
Butsugan, Yasuo
Indium-mediated reaction of 1,3-dichloropropene with aldehyde gave syn-chlorohydrin predominantly. A similar reaction of 1,3-dibromopropene gave vinyloxirane and homoallyl alcohol; the former is formed from γ-bromoallylindium via the corresponding bromohydrin, and the latter is considered to be derived from a unique allylic diindium reagent, 3,3-diindiopropene.
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