Tetrahedron p. 2901 - 2908 (1987)
Update date:2022-08-05
Topics:
Donaldson, William A.
The cleavage of the title compounds (7) in methanolic potassium hydroxide gives mixtures of olefins and α-methoxyolefins in good yields.The ratio of the products is dependent on the size of the carbocyclic ring.The mechanism proposed involves cleavage of 7 to the corresponding allylic chloride (8).Solvolysis of the chloride gives the α-methoxyolefin.Alternatively, oxidative addition of 8 to Pd(O) generates a new ?-allyl complex which affords the olefin product upon subsequent cleavage.
View Morepuyang hongda shengdao new material co.,ltd.
Contact:+86-393- 4896278
Address:No.29 East Zhongyuan Road
Contact:+86+21-58956006 15800617331
Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
HANGZHOU YUNUO CHEMICAL CO.,LTD
website:http://www.yunuochem.com
Contact:0571-83715115
Address:hangzhou
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)
Contact:86 512 57910558
Address:qianjin M road
Doi:10.1016/j.tetasy.2008.12.017
(2008)Doi:10.1021/ol900194v
(2009)Doi:10.1016/j.bmcl.2010.05.082
(2010)Doi:10.1016/0223-5234(94)90211-9
(1994)Doi:10.1055/s-0033-1340076
(2013)Doi:10.1039/c3cc47996j
(2014)
