Preparation of Dimethyl (1-Formylalkyl)phosphonates via Singlet Oxygen Adducts

DOI: 10.1055/s-1987-28057

Source and publish data:

Synthesis p. 716 - 718 (1987)

Update date:2022-07-31

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Authors:

Yamashita, Mitsuji

Nomoto, Hiroyuki

Imoto, Hiroyuki

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Article abstract of DOI:10.1055/s-1987-28057

The nitro group of dimethyl (1-nitromethylalkyl)phosphonates is conveniently converted into a formyl group by reaction with singlet oxygen to give dimethyl (1-formylalkyl)phosphonates. (1-Formylbutyl)diphenylphosphine oxide is prepared by the same reactio

Full text of DOI:10.1055/s-1987-28057

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