STEREOCONTROLLED TOTAL SYNTHESIS OF (+/-)-NORPATCHOULENOL AND TWO METABOLITES OF PATCHOULI ALCOHOL, (+/-)-HYDROXY PATCHOULI ALCOHOL AND THE CORRESPONDING (+/-)-CARBOXYLIC ACID

DOI: 10.1016/S0040-4020(01)90019-5

Source and publish data:

Tetrahedron p. 825 - 834 (1987)

Update date:2022-07-31

Topics:

Authors:

Niwa, Haruki

Hasegawa, Takashi

Ban, Norikazu

Yamada, Kiyoyuki

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Article abstract of DOI:10.1016/S0040-4020(01)90019-5

The first total synthesis of the two biooxidation products of patchouli alcohol (2), (+/-)-hydroxy patchouli alcohol (3) and the corresponding (+/-)-carboxylic acid 4, has been achieved in highly stereocontrolled manners.Synthesis of (+/-)-norpatchoulenol (1), the real odoriferous substance of patchouli oil, has been accomplished by the biogenetic route via (+/-)-3 and (+/-)-4.

Full text of DOI:10.1016/S0040-4020(01)90019-5

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