Journal of Organic Chemistry p. 2525 - 2533 (1988)
Update date:2022-08-02
Topics:
Yoshida, Jun-ichi
Sakaguchi, Kazuhiko
Isoe, Sachihiko
The electrochemical oxidation of 1,3-diketones and 2-substituted 1,3-diketones in the presence of olefin gave the <3 + 2> cycloadducts, dihydrofuran and tetrahydrofuran derivatives, respectively.A mechanism involving electrooxidative formation of the radical intermediate from the diketone followed by addition to the olefin has been proposed.
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