Dual photodissociation of axial ligands in six-coordinate cobalt(III) tetraphenylporphyrins

DOI: 10.1021/j100355a017

Source and publish data:

Journal of Physical Chemistry p. 6655 - 6659 (1989)

Update date:2022-07-29

Topics:

Authors:

Hoshino Hoshino

Kogure Kogure

Amano Amano

Hinohara

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Article abstract of DOI:10.1021/j100355a017

Six-coordinate cobalt(III) tetraphenylporphyrins, XCo^IIITPP(Py) (Py = pyridine and X = N₃, Cl, and SCN), exhibit dual photoreactions: the photoejection of axial pyridine and the photochemical homolysis of the X-Co bond. The former is

Full text of DOI:10.1021/j100355a017

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