Efficient and Flexible Syntheses of Paraconic Esters and Other Highly Substituted Furanone Derivatives from Methyl 2-Siloxycyclopropanecarboxylates

DOI: 10.1021/jo00246a010

Source and publish data:

Journal of Organic Chemistry p. 2440 - 2450 (1988)

Update date:2022-08-04

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Authors:

Brueckner, Christiane

Reissig, Hans-Ulrich

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Article abstract of DOI:10.1021/jo00246a010

Deprotonation of methyl 2-siloxycyclopropanecarboxylates 1 with lithium diisopropylamide and reaction of the resulting enolates with carbonyl compounds produce trifunctional cyclopropane derivatives.These primary adducts can only be isolated with good yie

Full text of DOI:10.1021/jo00246a010

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Product name:Cyclopropanecarboxylic acid, 2-(1,1-dimethylethyl)-1-(hydroxyphenylmethyl)-2-[(trimethylsilyl)oxy]-, methyl ester

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