Photostimulated Reaction of 1-Halo- and 1,4-Dihalobicyclooctanes with Diphenylphosphide Ions by the SRN1 Mechanism

Article abstract of DOI:10.1021/jo00248a021

The reaction of 1-iodobicyclo<2.2.2>octane (5) with diphenylphosphide ions (6) in liquid ammmonia gives in 20 min of irradiation and after oxidation of the reaction product good yields of (bicyclo<2.2.2>oct-1-yl)diphenylphosphine oxide (8).Although there