Journal of Organic Chemistry p. 3309 - 3312 (1988)
Update date:2022-08-04
Topics:
Taylor, Stephen K.
Blankespoor, Curtis L.
Harvey, Suzanne M.
Richardson, Lynell J.
The intramolecular cyclization of aryl groups to tertiary epoxide position was investigated, and the results were used to test the applicability of Baldwin's rules to this specific class of reactions.As a probe into mechanism of reactions studied earlier, the cyclizations of some meta-substituted 1,2-epoxy-5-phenylpentanes were examined to determine positional selectivities.The data obtained were compared with those of other studies, and comments are made on the reaction mechanism.
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