Equilibrium and Kinetic Acidities of Benzylic Ketones. Application of the Marcus Equation to the Deprotonation of Carbon Acids

DOI: 10.1021/ja00220a046

Source and publish data:

Journal of the American Chemical Society p. 4008 - 4017 (1988)

Update date:2022-08-04

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Authors:

Bunting, John W.

Stefanides, Dimitrios

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Article abstract of DOI:10.1021/ja00220a046

Equilibrium constants and rates of ketone-enolate ion equilibration have been measured for the deprotonation of eight 3-(X-phenylacetyl)pyridines 1 (pK_a 13.2 for X = H), ten 4-(X-phenylacetyl)pyridines 2 (pK_a 12.2 for X = H), nine 1-

Full text of DOI:10.1021/ja00220a046

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