Coupling Reaction of Allyl Sulfones Using Sodium Hydroxide in Liquid Ammonia

DOI: 10.1246/cl.1987.1939

Source and publish data:

Chemistry Letters p. 1939 - 1942 (1987)

Update date:2022-07-31

Topics:

Authors:

Takikawa, Yuji

Osanai, Kimiko

Sasaki, Satoshi

Shimada, Kazuaki

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Article abstract of DOI:10.1246/cl.1987.1939

Vinylcyclopropane derivatives containing two isomers were respectively obtained in good yields in the reactions of 3-methyl-2-butenyl, geranyl, and neryl p-tolyl sulfones with NaOH in liquid ammonia.On the other hand, the reaction with crotyl p-tolyl sulfone gave 2-ethyl-1,3-di-p-toluenesulfonylpropane in good yield.

Full text of DOI:10.1246/cl.1987.1939

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