New Method for Oxidative Carbon-carbon Bond Formation by the Reaction of Allyl Ethers, 2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ) and Silyl Carbon Nucleophiles

DOI: 10.1246/cl.1987.1811

Source and publish data:

Chemistry Letters p. 1811 - 1814 (1987)

Update date:2022-09-26

Topics:

Authors:

Hayashi, Yujiro

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1987.1811

Allyl ethers are oxidized by DDQ to generate the corresponding cationic species, which in turn react with silyl carbon nucleophiles in the presence of a catalytic amount of lithium perchlorate to afford the coupled products in a one-pot procedure in good

Full text of DOI:10.1246/cl.1987.1811

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