Tetrahedron p. 5261 - 5274 (1987)
Update date:2022-07-29
Topics:
Ojika, Makoto
Wakamatsu, Kazumasa
Niwa, Haruki
Yamada, Kiyoyuki
The structure of ptaquiloside (I), a potent carcinogenic compound isolated from bracken fern, Pteridium aquilinum var. latiusculum has been elucidated on the basis of chemical and spectral evidence.The dienone 3 generated from 1 under alkaline conditions was shown to be a strong alkylating agent.For the purpose of obtaining the preliminary information on chemical modification of biopolymers such as proteins and DNA with the dienone 3, reactions of 3 with amino acids, nucleosides, and nucleotides have been carried out and the alkylated products have been characterized.
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Doi:10.1016/S0040-4039(00)95578-3
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(1958)Doi:10.1016/j.saa.2013.01.028
(2013)
