Tetrahedron Letters p. 4147 - 4148 (1987)
Update date:2022-08-05
Topics:
Burke, Steven D.
Chandler, Arthur C.
Nair, Mangalam S.
Campopiano, Onorato
Conversion of (R)-3-benzyloxy-2-methylpropionaldehyde (4) to the erythronolide B C(7)-C(13) subunit 13 in the 15percent overall yield is described.Chelation-controlled carbonyl additions and a dioxanone-to-dihydropyran Claisen rearrangement are key steps.
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(2009)Doi:10.3184/174751912X13353579628083
(2012)Doi:10.1007/BF00479365
(1987)Doi:10.1016/s0022-328x(96)06598-9
(1997)Doi:10.1016/S0022-328X(00)85812-X
(1981)Doi:10.1021/jo01063a603
(1961)
