Homogeneous decarbonylation of ethyl formate at rhodium. Evidence for the formation of a cis-hydride(ethoxycarbonyl) intermediate through C-H bond cleavage

DOI: 10.1016/0022-328X(88)80349-8

Source and publish data:

Journal of Organometallic Chemistry p. C9 - C11 (1988)

Update date:2022-08-03

Topics:

Authors:

Bianchini, Claudio

Peruzzini, Maurizio

Vizza, Frencesco

Zanobini, Fabrizio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(88)80349-8

The 16-electron fragment <(NP3)Rh>⁺ inserts into the sp² C-H bond of ethyl formate to give the octahedral complex cation <(NP3)Rh(H)(CO2Et)>⁺ which can be isolated in the solid state as SO3CF3^- salt.Thermal decomposition of the cis-hydride(ethoxycarbonyl) complex in benzene gives EtOH and the carbonyl <(NP3)RhCO>(SO3CF3) (NP3 = N(CH2CH2PPh2)3).

Full text of DOI:10.1016/0022-328X(88)80349-8

Products guided by the article

Product name:{(NP₃)RhCO}(SO₃CF₃)

Cas No:114900-39-9

R&D Labs maybe for 114900-39-9

Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China
HUNAN OUYA BIOLOGICAL CO.,LTD

Contact:+8613400661290

Address:No 908,Kangwan Rd, Liuyang Economic
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
ChengduChroma-BiotechCo.,Ltd.

Contact:86-28-61993785

Address:No.70-13-21, North Section, Erhuan

Relevant to this article

A convenient enantiospecific route towards bioactive merosesquiterpenes by cationic-resin-promoted Friedel-Crafts alkylation with α,β-enones

Doi:10.1002/ejoc.200801174
(2009)
Silver-catalysed Doyle-Kirmse reaction of allyl and propargyl sulfides

Doi:10.1039/b822584b
(2009)
REACTIONS WITH α-THIOCARBAMOYLCINNAMONITRILES: SYNTHESIS OF PYRAZOLO<1,5-a>PYRIMIDINES

Doi:10.1016/S0040-4020(01)85113-9
(1988)
Carbonic anhydrase inhibitors. Inhibition of the Rv1284 and Rv3273 β-carbonic anhydrases from Mycobacterium tuberculosis with diazenylbenzenesulfonamides

Doi:10.1016/j.bmcl.2009.07.088
(2009)
Syn-epoxidation of Chiral (Z)-2-Methyl-3-alkenal Acetal via Stereo-selective Bromohydrin Formation

Doi:10.1246/cl.1987.2133
(1987)
Enantioselective, copper(I)-catalyzed three-component reaction for the synthesis of β,γ-alkynyl α-amino acid derivatives

Doi:10.1016/j.tetasy.2009.01.006
(2009)

Article Doi