Journal of Organometallic Chemistry p. C9 - C11 (1988)
Update date:2022-08-03
Topics:
Bianchini, Claudio
Peruzzini, Maurizio
Vizza, Frencesco
Zanobini, Fabrizio
The 16-electron fragment <(NP3)Rh>+ inserts into the sp2 C-H bond of ethyl formate to give the octahedral complex cation <(NP3)Rh(H)(CO2Et)>+ which can be isolated in the solid state as SO3CF3- salt.Thermal decomposition of the cis-hydride(ethoxycarbonyl) complex in benzene gives EtOH and the carbonyl <(NP3)RhCO>(SO3CF3) (NP3 = N(CH2CH2PPh2)3).
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Doi:10.1002/ejoc.200801174
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(2009)
