Intramolecular, Reversible C-H Oxidative Addition-Reductive Elimination at Rhodium. Reaction of the Intermediate with Different Types of C-H Bonds and Dihydrogen

DOI: 10.1039/c39870000971

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Journal of the Chemical Society. Chemical communications p. 971 - 973 (1987)

Update date:2022-09-26

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Authors:

Bianchini, Claudio

Meli, Andrea

Peruzzini, Maurizio

Zanobini, Fabrizio

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Article abstract of DOI:10.1039/c39870000971

The ortho-metallated complex <((Ph2PCH2CH2)2N(CH2CH2PPhC6H4))RhH>(SO3CF3) thermally or chemically undergoes reductive elimination of the substituted phenyl group; the N(CH2CH2PPh2)3Rh⁺ fragment thus formed is stabilized by CO, halides, C2H4, or

Full text of DOI:10.1039/c39870000971

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Product name:{((C₆H₅)2PCH₂CH₂)3NRhCl₂}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂)3NRhCl₂}(SO₃CF₃)

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