Intramolecular, Reversible C-H Oxidative Addition-Reductive Elimination at Rhodium. Reaction of the Intermediate with Different Types of C-H Bonds and Dihydrogen

DOI: 10.1039/c39870000971

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 971 - 973 (1987)

Update date:2022-09-26

Topics:

Authors:

Bianchini, Claudio

Meli, Andrea

Peruzzini, Maurizio

Zanobini, Fabrizio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870000971

The ortho-metallated complex <((Ph2PCH2CH2)2N(CH2CH2PPhC6H4))RhH>(SO3CF3) thermally or chemically undergoes reductive elimination of the substituted phenyl group; the N(CH2CH2PPh2)3Rh⁺ fragment thus formed is stabilized by CO, halides, C2H4, or

Full text of DOI:10.1039/c39870000971

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{((C₆H₅)2PCH₂CH₂)3NRhCl₂}⁽¹⁺⁾*SO₃CF₃^(1-)={((C₆H₅)2PCH₂CH₂)3NRhCl₂}(SO₃CF₃)

Cas No:115030-05-2

R&D Labs maybe for 115030-05-2

Guangxi Shanyun Biochemical Science and Technology Co., Ltd

Contact:+86-0772--6828887

Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china
Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China

Relevant to this article

A recyclable magnetic nanoparticles supported antimony catalyst for the synthesis of N-substituted pyrroles in water

Doi:10.1016/j.apcata.2013.03.005
(2013)
Metal-Free Visible-Light-Mediated Desulfurization and Aromatization of Dihydropyrimidine-2-thiones for Synthesis of 2-Unsubstituted Pyrimidines

Doi:10.1055/s-0036-1588401
(2017)
L-METHIONINE OXIDATION: NOVEL AND UNANTICIPATED TRANSFORMATIONS WITH 4-tBUTYL IODOXYBENZENE

Doi:10.1016/S0040-4020(01)87715-2
(1987)
Controlled release of hydrogen sulfide significantly reduces ROS stress and increases dopamine levels in transgenic: C. elegans

Doi:10.1039/c9cc05153h
(2019)
A New Synthesis of Substituted Dienes and its Application to an Alkylated Taxane Model System

Doi:10.1039/c39870001540
(1987)
From carbohydrates to carbocycles. 2. A free radical route to Corey lactone and other prostanoid intermediates

Doi:10.1021/jo00254a020
(1988)

Article Doi