
Journal of the Chemical Society, Dalton Transactions p. 2353 - 2360 (1992)
Update date:2022-08-04
Topics:
Bookham, Jonathan L.
McFarlane, William
Thornton-Pett, Mark
Addition reactions between ERH2 (E = P or As; R = Ph, CH2CH2CN, Bu or C6H2tBu3-2,4,6) and (Ph2P)2C=CH2 or (Ph2P)2C=CHR' (R'= H or Me) yield the triphosphines (Ph2P)2CHCHR'ERH and the pentaphosphines <(Ph2P)2CHCH2>2ER and (Ph2P)2CHCH(Me)P(Ph)CH2CH(PPh2)2.T
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