International Journal of Chemical Kinetics p. 505 - 514 (1997)
Update date:2022-08-04
Topics:
Burcat, Alexander
Dvinyaninov, Michael
Mixtures of cyclopentadiene diluted with argon were used to investigate its decomposition pattern in a single pulse shock tube. The temperatures ranged from 1080 to 1550 K and pressures behind the shock were between 1.7-9.6 atm. The cyclopentadiene concentrations ranged from 0.5 to 2%. Gas-chromatographic analysis was used to determine the product distribution The main products in order of abundance were acetylene, ethylene, methane, allene, propyne, butadiene, propylene, and benzene. The decomposition of cyclopentadiene was simulated with a kinetic scheme containing 44 species and 144 elementary reactions. This was later reduced to only 36 reactions The ring opening process of the cyclopentadienyl radical was found to be the crucial step in the mechanism. 1997 lohn Wiley and Sons, Inc.
View MoreShanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd
Contact:+86-0372-3662335 +86-0372-3661988
Address:hanling industrial park anyang
KAIYUAN CHEMICAL COMPANY LIMITED.
website:http://www.kaiyuanchem.com
Contact:+86-22-59891255/66/77
Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
HAINAN JINYING IMPORT AND EXPORT CO. LTD
Contact:+86-898-32875423
Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA
Fusilin chemical science & technology co., ltd.
Contact:532-80698166/86057573, +86-400-669-7885
Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Doi:10.3184/030823408X338701
(2008)Doi:10.1021/tx970217f
(1998)Doi:10.1055/s-1989-27312
(1989)Doi:10.1021/om020406f
(2002)Doi:10.1021/ja0102742
(2001)Doi:10.1021/jm0500020
(2005)